Penn State University / College of Education.

Investigations

Lesson 8

Title: Human-Produced Greenhouse Gases and the "Enhanced" Greenhouse Effect

Overview & Outcomes:

Investigations Lesson 6 focused on the natural phenomena known as the "greenhouse effect." Investigations Lesson 7 dealt with the role the atmosphere plays in temperature regulation-the greenhouse effect. This lesson helps students distinguish between the "greenhouse effect" and the "enhanced greenhouse effect," the latter being due to the human production of greenhouse gases. It is important to note that there are two ways humans can increase the amounts of greenhouse gases. First, the processes that increase gases can be accelerated and second, the processses that remove gases (the sinks) can be decreased. Human production of CO2 currently is responsible for the majority of the enhanced greenhouse effect. Investigations Lesson 9 focuses on alternative conceptions many students have surrounding ozone depletion and the greenhouse effect. Investigations Lesson 10 is a laboratory exercise on CO2.

This lesson helps learners:

The concept map shows model relationships among concepts this lesson seeks to develop. Concepts introduced in this lesson are bolded on that concept map and concepts from other lessons are in plain text (not bolded).

Background Notes for the Teacher:

Content. Human activity that results in significant increases in greenhouse gas emissions is enhancing the greenhouse effect on earth. Accordingly, human-produced greenhouse gases are giving rise to what has become known as the "enhanced" greenhouse effect. The enhanced greenhouse effect is also labelled by scientists as "greenhouse warming". An important point is that it is the enhanced greenhouse effect (or "greenhouse warming"), not the "greenhouse effect," that may cause global warming.

Human-produced greenhouse gases and their natural and human-produced sources are outlined below. The greenhouse gas "water vapor" is not included in this presentation or in the instructional procedures. However, it does originate from natural sources as well as human activity (e.g., irrigation). Water vapor has been excluded from the instruction in this lesson because a study of its contribution to the enhanced greenhouse effect also involves clouds and yet warrants considerable study by scientists. A brief presentation on water vapor and clouds follows.

Water Vapor and Clouds - Scientists presently are uncertain about the degree to which water vapor enhances the greenhouse effect, and the contribution of water vapor is intertwined with other issues, such as increases in other greenhouse gases and the role clouds play in the greenhouse effect. For example, as human activity contributes more carbon dioxide and other greenhouse gases to the atmosphere, the atmosphere likely will warm. In turn, a warmer atmosphere results in more evaporation, and probably, an increase in the amount of water vapor in the atmosphere. More water vapor in the atmosphere leads to more absorption of infrared energy and also can lead to more clouds. Clouds, due to their water vapor content, absorb infrared energy emitted by earth: Through this phenomena, clouds enhance the greenhouse effect. However, clouds also reflect back to space some of the incoming solar radiant energy, and thereby decrease the amount of visible light that is absorbed and subsequently re-emited as infrared energy by earth's surface. The latter phenomena would lessen, not enhance the greenhouse effect. Put another way, the reflection of incoming solar radiation by clouds contributes a "negative feedback" to the enhanced greenhouse effect. The role of clouds in the enhanced greenhouse effect depends also on the type of clouds, where they are located, and other factors, which scientists need to learn more about. However, there is no doubt that clouds are a very important consideration in forcasting the probability and severity of global warming.

Carbon Dioxide: CO2


Natural - There is a net balance of zero in nature of CO2 because CO2 is removed from the atmosphere by a complex network of natural sinks. Most CO2 is absorbed in the atmosphere through photosynthesis of vegetation on land and plankton in the sea, and returned to the atmosphere through decomposition or consumption of vegetation and plankton. About one third of the CO2 presently being released (some CO2 is also produced in volcanic emissions) is absorbed by the oceans.

Human. The largest source of CO2 is combustion of fossil fuels (power plants, factories, automobiles). The second largest source is the conversion of forested areas to pasture and agricultural use. CO2 is released through the burning and decay of cleared vegetation and soil organic matter, and deforestation removes a CO2 sink or uptake. CO2 is also released during the manufacture of cement.

Methane: CH4


Natural. Methane is produced by bacteria in wetlands and in animals, especially wild ruminants (e.g., reindeer) and termites.

Human. Sources include rice paddies, municipal and industrial landfills, domesticated ruminants (e.g., cattle, sheep), incomplete combustion during biomass burning, and fossil fuel production (natural gas wells, coal mining).

Nitrous Oxide: N2O


Natural. Nitrous oxide is produced and consumed as part of the nitrogen cycle in biological processes in the soil and oceans.

Human. Sources include combustion of fossil fuels (automobile exhaust), use of nitrogenous fertilizers, and biomass burning in the tropics.

Tropospheric Ozone: O3


Natural. As indicated in Investigations Lesson 4 tropospheric ozone is produced via photochemical reactions of carbon monoxide (CO), methane (CH4) and other hydrocarbons (ozone precursors) in the presence of nitrogen oxides (NOx). Other natural sources of tropospheric ozone include lightening and natural forest fires (biomass burning).

Human. Although ozone in the lower atmosphere does not come directly from motor vehicles, they are major sources of ozone precursors throughout the industrialized world. Increased ozone contributions in the troposphere are attributed to photochemical reactions involving primary pollutants (CO, NO, SO2, and hydrocarbons) emitted as a consequence of the incomplete combustion of fossil fuels from industrial plants, homes, and most importantly from motor vehicles. Biomass burning (destruction of the rain forests) also contributes precursors to ozone.

Chlorofluorocarbons: CFCs


Natural. There is no natural source. CFCs are human-made compounds.

Human. CFCs are human-made products released when using aerosol propellants, refrigerants, coolants, and foam-blowing agents. Aerosols (e.g., spray cans) in the U.S. have not contained CFCs since 1979. The remainder of these background notes, as well as the notes and resource materials listed for Investigation Lesson 3, provide additional information on CFCs and the phase out of these substances through the use of CFC substitutes (e.g., HCFCs and HFCs).

In the chart that follows, natural levels of these gases in the atmosphere are compared to levels as a result of human activity. Note also the atmospheric lifetime (residence time), the annual rate of increase, and the relative contribution of each gas to the human-produced (anthropogenic) greenhouse effect. Carbon dioxide accounts for greater than half of the warming potential caused by human activity. Methane accounts for approximately 15% of the contribution to the human-produced greenhouse effect but molecule for molecule, CH4 traps heat 20-30 times more efficiently than CO2. Nitrous oxide is a long lasting gas which eventually reaches the stratosphere and helps destroy the ozone layer. CFCs are the most powerful of the greenhouse gases and are increasing at the fastest rate (one CFC molecule has about 20,000 times the heat-trapping power of a CO2 molecule). Tropospheric O3 has the shortest residence time but is increasing at a rate second only to CFCs.

As described in Investigation Lesson 3, CFCs also destroy ozone in the ozone layer: Each CFC molecule can destroy 10,000 or more O3 molecules in the stratosphere. However, to be clear: The thinning of the ozone layer does not enhance the greenhouse effect or cause global warming. The latter is important to point out , as the idea that the "ozone hole" causes global warming, or that CFCs cause global warming by destroying the ozone layer, are misconceptions commonly held by students. However, the resulting increase in UV rays at ground level is biologically damaging and has become an international concern. Because of this, recently all of the countries (including the United States) who are major developers and users of CFCs, have signed an agreement to phase out these substances and have been rapidly reducing their use of CFCs by employing CFC substitutes. Given this big reduction in CFC use, how is it, then, that CFCs are increasing in our atmosphere at a rate faster than any of the other greenhouse gases (as note above)?

One reason is that CFCs have a very long atmospheric lifetime: Because they stay in the atmosphere from 60 to 100 years, a reduction in use will not reduce decrease the amount in the atmosphere for many year. Another more important reason was introduced in Investigation Lesson 3: CFCs are still escaping into the atmosphere from products in junkyards and landfills that contain CFCs, e.g., refrigerators, freezers, and some types of foam products.

CFC substitutes include HCFCs and HFCs. Employing these substitutes as opposed to CFCs is certainly a step in the right direction, as they have considerably less or no ozone destroying capacity and a shorter atmospheric lifetime. However, some of these substitutes, such as HCFCs and HFCs, still have a powerful heat-trapping capacity, i.e. absorb infrared energy emitted by earth. Therefore, some of these substitutes are considered to be human-produced greenhouse gases that do enhance the greenhouse effect and can contribute to global warming.

CO2CH4N2OCFCSO3
<---------------------------ppb-------------------------->
(parts per billion)
Natural level in atmosphere:(Pre-industrial levels in parts per billion [ppb] by volume at surface)280,000790288010
Level in atmosphere as result of human activity: (Data of 1991; ppb)353,000172031076*20-40
Atmospheric Lifetime50-200 yr10 yr150 yr60-100 yrwks-mnths
Present Annual Rate of Increase0.5%0.9%0.3%4%0.5-2.0%
Contribution to enhanced greehouse effect:60%15%5%12%8%**

*Refers only to the sum of the amount of two CFCs: CFC-11 and CFC-12. Collectively, the amount of all CFCs as of 1991 was approximately 85 ppb.

**Although this report gives a specific quantity for the contribution of tropospheric ozone to the greenhouse effect, other reports give a range (e.g.. 5-10%) or do not give a specific quantity. In reference to the latter, the IPCC (Inter-governmental Panel for Climate Change) report of 1992 recognizes the contribution of tropospheric ozone to the greenhouse effect, but does not feel that data at present is sufficient to quantify this.

Students in the expert groups for the various human-produced greenhouse gases should be called upon as experts in future lessons to give specific data as needed about the different gases. The expert students should become an important information resource for the class.

Additional Teachers References.

  1. Caplan, R. (1990). Our Earth, Ourselves. New York: Bantam Books, p. 25-31.
  2. Crane, R. and Borza, K. (1993). Global Warming. University Park, PA: The Pennsylvania State University.
  3. Mackenzie, F. and Mackenzie, J. (1995). Our Changing Planet. New Jersey: Prentice-Hall.
  4. MacKenzie, J. and Walsh, M. (1990). DRIVING FORCES: Motor Vehicle Trends and Their Implications for Global Warming, Energy Strategies, and Transportation Planning. Washinton, DC: World Resources Institute, (New York: Oxford University Press). p. 7.
  5. Office of Interdisciplinary Studies. (Spring 1991). EarthQuest: Atmospheric Trace Gases That Are Relatively Active and of Significance to Global Change, 5(1).
  6. Phillips, P. and Pickering, P. (1991, March). Ozone in the atmosphere: II The lower atmosphere. School Science Review Part 2, 72(260), p. 79-86.
  7. World Resources Institute. (1991).World Resources 1990-91: A Guide to the Global Environment (Teacher's Guide) . New York: Oxford University Press.

Materials:

For each group.

  1. Packet of materials about each gas for expert groups: a. Suggested materials included b. Teacher/librarian constructed packets c. Resource materials in classroom
  2. HUMAN-PRODUCED GREENHOUSE GASES chart for each home group

For each student.

  1. HUMAN-PRODUCED GREENHOUSE GAS:_____

Preparation:

  1. Prepare resource materials.
  2. Reproduce handouts.

Instructional Procedures: (2 Days, 40 minutes each)

Day 1. (40 minutes)

  1. Prepare for a jigsaw II cooperative learning activity by dividing students into home groups. Distribute the HUMAN-PRODUCED GREENHOUSE GAS:___ form to each student. Next, assign each member one or more of the human-produced greenhouse gases.
  2. Students responsible for the same gas should then meet in their expert groups. They should examine the resource materials and each complete the handout, HUMAN-PRODUCED GREENHOUSE GAS:___ . The expert groups assigned to CFCs and tropospheric ozone should also examine the booklet used in Investigation Lesson 3: Our Ozone Sheild. An option would be to have students also develop questions for a quiz the next class period.
  3. In home groups, experts should complete their column of the HUMAN PRODUCED GREENHOUSE GASES chart and teach other group members about their greenhouse gas.
  4. Completed charts should be displayed in each group's display area or bulletin board for easy reference and reinforcement.

Day 2. (40 minutes)

  1. The next class period may begin with a short quiz if questions on the gases were generated during the previous class period by expert groups. If charts have been displayed, they may need to be moved from view during the quiz.
  2. Students should return to home groups and discuss which gas they feel is the worst human-produced greenhouse gas and why. A designated recorder should put the responses into a one-page position statement.
  3. Each home group should present their position statement to the class. The reporter is chosen by the teacher immediately before the presentation to encourage individual accountability. In a class discussion, other class members should provide feedback.
  4. If the group decides, they may change their position statements before handing in.

Optional.

  1. If a storyboard is used, different sources of these gases could be added to the board.
  2. To help students realize the significance of different residence times of these gases, an activity using different types of candy could be done. Distribute candy with different solubilities (malted milk balls, M&Ms, jawbreakers, etc.) to students in groups or in class. Ask students to record how long it is taking their candy to dissolve naturally. Students should compare differences and then relate that to the different residence times of the human-produced greenhouse gases.

Assessment/Portfolio Items:

The following pieces of evidence from the lesson could be included in a student's portfolio:

Journal Entry

. Of all the group position statements that you heard today, which one did you like the most and why?


HUMAN-PRODUCED GREENHOUSE GAS:_____

Expert:______________________________

SOURCES:

NATURAL LEVEL IN ATMOSPHERE:

LEVEL IN ATMOSPHERE AS A RESULT OF HUMAN ACTIVITY:

ATMOSPHERIC LIFETIME:

PRESENT ANNUAL RATE OF INCREASE:

CONTRIBUTION TO ENHANCED GREENHOUSE EFFECT:

OTHER INFORMATION:


Group Members
1. _______________________3. _______________________
2. _______________________4. _______________________
CH4
CO2N2OCFCsO3
SOURCES....
NATURAL LEVEL IN ATMOSPHERE....
LEVEL IN ATMOSPHERE AS A RESULT OF HUMAN ACTIVITY:....
ATMOSPHERIC LIFETIME:....
PRESENT ANNUAL REATE OF INCREASE:....
CONTRIBUTION TO ENHANCED GREENHOUSE EFFECT:....


HUMAN-PRODUCED GREENHOUSE GASES

(Adapted from Crane, R. and Borza, K. (1993). Global Warming.
University Park, PA: The Pennsylvania State University.)

Human-produced greenhouse gases include carbon dioxide, methane, nitrous oxide, and chlorofluorocarbons. They are produced both naturally and by human activity and these sources will be examined.

Carbon Dioxide: CO2

Natural Source. Plants absorb CO2 from the atmosphere through photosynthesis and return CO2 to the atmosphere through respiration and decomposition of vegetation. The atmosphere also exchanges CO2 with the oceans. Volcanic emissions contain carbon dioxide and account for some of the natural contribution of CO2 to the atmosphere. In nature, the amount of CO2 produced is balanced by the amount of CO2 removed naturally from the atmosphere resulting in no increase in CO2 within the atmosphere.

Human Source. The amount of CO2 in the atmosphere remained constant for millions of years until the 1800s when the Industrial Revolution began. Large amounts of CO2 began to be produced from the burning of fossil fuels upsetting the natural balance. The largest human source of CO2 in the atmosphere is the burning of fossil fuels from vehicles or factories. The second largest source of CO2 is land-use change from forest to agriculture. CO2 is released through the burning and decay of plants and the loss of forest represents the loss of a sink or uptake for CO2. Much more CO2 is added to the atmosphere than is removed resulting in a net increase of CO2.

Methane: CH4

Natural Source. Bacteria produce methane in wetlands, rice paddies, and within ruminants (cows, deer) and termites.

Human Source. Rice paddies and municipal and industrial landfills produce methane. Other sources include domesticated ruminants (cows, sheep), incomplete combustion during biomass burning in the tropics, fossil fuel production, leaks from natural gas pipelines, and coal mining.

Nitrous Oxide: N2O

Natural Source. Nitrous oxide is produced and consumed by microbes in soil and oceans.

Human Source. Three main sources of N2O are the combustion of fossil fuels, use of nitrogen-containing fertilizers, and biomass burning in the tropics.

Chlorofluorocarbons: CFCs

Natural Source. There is no natural source. CFCs are human-made compounds.

Human Source. CFCs are human-made products released when using aerosol propellants, refrigerants, coolants, and foam-blowing agents. AEROSOLS (e.g., SPRAY CANS) IN THE U.S. HAVE NOT CONTAINED CFCs SINCE 1979. The remainder of these background notes, as well as the notes and resource materials listed for Investigation Lesson 3, provide additional information on CFCs and the phase out of these substances through the use of CFC substitutes (e.g., HCFCs and HFCs).


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